How To Use Allylic In A Sentence
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Oxatriquinacene, the first stable allylic oxonium ion, is more reactive than oxatriquinane yet significantly more stable than simple alkyl oxonium salts.
Chemical & Engineering News: Latest News
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Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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Abstraction of the double allylic hydrogen of CDH by triplet BZP would lead to a radical pair; this could explain the formation of benzene and all the detected minor photoproducts.
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The allylic alcohol is oxidised to the epoxide (R) - glycidol using the oxidising agent tertiary butylhydroperoxide in the presence of a catalyst.
The Nobel Prize in Chemistry 2001 - Information for the Public
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Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol).
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Oxidation of alcohols to aldehydes and ketones Allylic and benzylic alcohols can be oxidized in presence of other alcohols using certain selective oxidants such as manganese dioxide (MnO2).
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An advantage of the new methods is the utilization of easily accessible allylic amine derivatives as monomer precursors.
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In complementary experiments, CHD and CHDCA were used as models for LA as they also have double allylic systems.
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The allylic oxidation of cyclohexene was the dominate reaction, and cyclohexene-2-one was obtained as the major product.
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Oxatriquinacene, the first stable allylic oxonium ion, is more reactive than oxatriquinane yet significantly more stable than simple alkyl oxonium salts.
Chemical & Engineering News: Latest News
-
Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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Decomposition of these primary photoproducts to give secondary products arising from allylic hydroperoxide degradation - either by Hock rearrangement or by alkenyl ether epoxidation - was also observed.
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He discovered one certain type of solvent called allylic alcohols that turned off the oxidation.
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An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol) carried out while she was at Merck.
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In 1980 he carried out successful experiments that led to a practical method for the catalytic asymmetric oxidation of allylic alcohols to chiral epoxides.
The Nobel Prize in Chemistry 2001 - Information for the Public
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The allylic alcohol is oxidised to the epoxide (R) - glycidol using the oxidising agent tertiary butylhydroperoxide in the presence of a catalyst.
The Nobel Prize in Chemistry 2001 - Information for the Public
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For substances containing allyl or allylic side chains a direct mechanism of action involving an allylic cation which then reacts with nucleophilic centers of nucleic acid bases has been discussed in the literature.
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Using allylic alcohol removes that chemical imperative for a company to make up their solutions and make the films very quickly.
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The new methods allow a wide range of poly analogs to be obtained in few steps, as the allylic precursors are readily available.