allylic

ADJECTIVE
  1. of or pertaining to the allyl radical
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How To Use allylic In A Sentence

  • Oxatriquinacene, the first stable allylic oxonium ion, is more reactive than oxatriquinane yet significantly more stable than simple alkyl oxonium salts. Chemical & Engineering News: Latest News
  • Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates. Irwin Rose - Autobiography
  • Abstraction of the double allylic hydrogen of CDH by triplet BZP would lead to a radical pair; this could explain the formation of benzene and all the detected minor photoproducts.
  • The allylic alcohol is oxidised to the epoxide (R) - glycidol using the oxidising agent tertiary butylhydroperoxide in the presence of a catalyst. The Nobel Prize in Chemistry 2001 - Information for the Public
  • Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates. Irwin Rose - Autobiography
  • An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol).
  • Oxidation of alcohols to aldehydes and ketones Allylic and benzylic alcohols can be oxidized in presence of other alcohols using certain selective oxidants such as manganese dioxide (MnO2). Recently Uploaded Slideshows
  • An advantage of the new methods is the utilization of easily accessible allylic amine derivatives as monomer precursors.
  • In complementary experiments, CHD and CHDCA were used as models for LA as they also have double allylic systems.
  • The allylic oxidation of cyclohexene was the dominate reaction, and cyclohexene-2-one was obtained as the major product.
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