How To Use Allyl In A Sentence
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The team had participants eat six grams of raw garlic and then tested not only for this VSC but others as well, including allyl mercaptan, methanethiol, allyl methyl disulfide and allyl disulfide.
Dr. Harold Katz: Advice and Explanations of Bad Breath From Experts
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In complementary experiments, CHD and CHDCA were used as models for LA as they also have double allylic systems.
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The biosynthesis of many important primary metabolites (such as cholesterol) proceed through intermediates that contain the allyl alcohol functional group.
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The onion family (including leeks, chives and scallions) is rich in allyl sulfides, which can help lower high blood pressure and show promise in protecting against cancers of the stomach and the digestive tract.
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This was heated with paraldehyde, whereby it was converted into allylpyridine (48 grammes), and this by reduction with sodium yielded alpha-propylpyridine, a body in almost every respect identical with coniine.
Scientific American Supplement, No. 623, December 10, 1887
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The allylic oxidation of cyclohexene was the dominate reaction, and cyclohexene-2-one was obtained as the major product.
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Mostly allyl methyl sulfide, which is a volatile sulfur compound VSC.
Dr. Harold Katz: Advice and Explanations of Bad Breath From Experts
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Slide 13: Common Names • the common names methylene, vinyl, and allyl are often used to show the presence of the following alkenyl groups Alk enyl Common IUPA C N ame Grou p N ame (Common name) Example Methylidenecyclopen tane Methylene CH2 = H2 C
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Some scientists believe the components in onions and garlic called allyl sulfides and bioflavonoids may be key to the research observations of generally lower incidence of cancer and heart disease in people who consume large amounts of garlic and onions, compared with those who eat less.
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Allyl-functional benzoxazine is synthesized with the allyl phenol produced by us. And the product is characterized and deduced by H-NMR, FTIR, MS and DSC.
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This project includes the provision of a new source for the abstraction of water from the River Mahon, at the tidal divide near Ballylaneen.
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Oxatriquinacene, the first stable allylic oxonium ion, is more reactive than oxatriquinane yet significantly more stable than simple alkyl oxonium salts.
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He was a regular attendant at Our Lady's Day Care Centre, Ballylanders and will be sadly missed by all the patrons.
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The colors of the palladium compounds of acetylene and allylene do not differ materially.
Transactions of the American Philosophical Society
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Consequently, antioxidants including ginsenosides Rb1 and Rg1, S-allyl cysteine sulphoxide (SACS), simvastatin (SVT) and vitamin E significantly abolished HAART 3-plex-induced inhibition of cholesterol efflux.
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However, a phytonutrient called diallyl sulfide DAS, one of the sulfide compounds that give garlic its characteristic smell, can inhibit the carcinogenic effects of PhIP.
The Fiber35 Diet
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They possess alike the same properties and characteristics, though in varying degrees, and they severally belong to the genus _Allium_, each containing "allyl," which is a radical rich in sulphur.
Herbal Simples Approved for Modern Uses of Cure
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Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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The yellow precipitate resulting was washed and afterwards decomposed by hydrochloric acid, allylene being then set free in a pure state.
Transactions of the American Philosophical Society
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Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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Aconitate isomerase catalyzes the interconversion of cis - and trans-aconitate by a 1, 3 allylic rearrangement that uses the (pro-S) hydrogens of the two substrates.
Irwin Rose - Autobiography
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Paisley stood on a picket line outside the Ballylumford power station in Larne and tried to persuade workers not to go in.
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In the study researchers from the Emory University School of Medicine were examining treatment options for cardiac patients, and their findings suggest that the treatment of hydrogen sulphide gas -- which is considered unstable and dissipates quickly -- could possible be replaced with injectable diallyl trisulphide, which helped reduce the amount of heart tissue damage by 61 percent.
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To establish a method for determination of H 2 O 2 in allyl chloride oxidation liquid oil - phase.
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Abstraction of the double allylic hydrogen of CDH by triplet BZP would lead to a radical pair; this could explain the formation of benzene and all the detected minor photoproducts.
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Initially our efforts concentrated on the two allyl side chains attached to the heterocycle via a methylene group.
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He's a pussycat reallyLarry, the Downing Street catTragically, endearingly, endearingly tragically or possibly tragically endearingly, news reaches us that No 10 has been furnished with a mouser from Battersea Cats' Home, to try to deal with its vermin problem insert own joke here.
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The allylic alcohol is oxidised to the epoxide (R) - glycidol using the oxidising agent tertiary butylhydroperoxide in the presence of a catalyst.
The Nobel Prize in Chemistry 2001 - Information for the Public
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As always please feel free to send any feedback (positive or negative) to ajet. [email protected] Paula Kerrigan Our Motle Cre y wof Write: rs AllyLo as Culture
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The allyl methyl sulfide and its related molecules combine with saliva and are exhaled for hours after consumption.
Dr. Harold Katz: Advice and Explanations of Bad Breath From Experts
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An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol).
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Oxidation of alcohols to aldehydes and ketones Allylic and benzylic alcohols can be oxidized in presence of other alcohols using certain selective oxidants such as manganese dioxide (MnO2).
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The production team and crew under the direction of the queen of panto in Ballylinan Bernie Dunne are once again looking forward to yet another busy run.
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An advantage of the new methods is the utilization of easily accessible allylic amine derivatives as monomer precursors.
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Mostly allyl methyl sulfide, which is a volatile sulfur compound VSC.
Dr. Harold Katz: Advice and Explanations of Bad Breath From Experts
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The areas serviced by the transport initiative include Scartaglen, Firies, Brosna, Kilflynn, Ballylongford and Knockanure.
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They contain diallyl sulfide and saponins, compounds that add distinctive flavors to our recipes and fight cancer and heart disease at the same time.
Archive 2007-10-01
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The team had participants eat six grams of raw garlic and then tested not only for this VSC but others as well, including allyl mercaptan, methanethiol, allyl methyl disulfide and allyl disulfide.
Dr. Harold Katz: Advice and Explanations of Bad Breath From Experts
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For substances containing allyl or allylic side chains a direct mechanism of action involving an allylic cation which then reacts with nucleophilic centers of nucleic acid bases has been discussed in the literature.
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Using allylic alcohol removes that chemical imperative for a company to make up their solutions and make the films very quickly.
Undefined
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The new methods allow a wide range of poly analogs to be obtained in few steps, as the allylic precursors are readily available.
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Garlic oil may protect your heart against damage, compound called allicin linked to cardiovascular health Diallyl trisulphide (DATS) may help 'release protective compounds to the heart' Monday, November 21 2011, 10:11 AM A potent-smelling component of garlic oil called diallyl trisulphide (DATS) may help release protective compounds to the heart.
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Epichlorohydrin is an important epoxide whose creation comes mainly from hydrochlorination of allyl chloride.
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The invention relates to a method for preparing solid oxide catalyst which is used to hydrogen transfer of acrolein gas to compose allyl alcohol.
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Pungent foods such as brussels sprouts, broccoli, onions, spices, coffee and chocolate, Profet says, nauseate some pregnant women because they contain compounds, such as allyl isothiocyanate in cabbage, that can interfere with fetal-organ formation.
Babies, Broccoli And Birth Defects
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The reactions of allylene closely resemble those of acetylene.
Transactions of the American Philosophical Society
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The allylic alcohol is oxidised to the epoxide (R) - glycidol using the oxidising agent tertiary butylhydroperoxide in the presence of a catalyst.
The Nobel Prize in Chemistry 2001 - Information for the Public
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Oxatriquinacene, the first stable allylic oxonium ion, is more reactive than oxatriquinane yet significantly more stable than simple alkyl oxonium salts.
Chemical & Engineering News: Latest News
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Diallyl trisulfide ( DATS ) is a major anticancer ingredient from the bulb of garlic of liliaceous plants.
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Allyl caproate 123-68-2 2032 170 kg 690 380 Allyl cyclohexyl propionate 2705-87-5 2026 180 kg
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Diallyl trisulfide ( DATS ) is a major anticancer ingredient from the bulb of garlic of liliaceous plants.
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Garlic oil may protect your heart against damage, compound called allicin linked to cardiovascular health Diallyl trisulphide (DATS) may help 'release protective compounds to the heart' Monday, November 21 2011, 10:11 AM A potent-smelling component of garlic oil called diallyl trisulphide (DATS) may help release protective compounds to the heart.
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Dead Lift degenerative problems dementia depression desaturase desserts, sugary detox exercise forinternalin the liverseven channels oftestingdetox formula diabetes adult-onsetand good fatsand inflammationand obesitydiallyl sulfide DAS
The Fiber35 Diet
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Objective Determination of allicin ( diallyl trisulfide ) in the allium complex with ? ? - cyclodextrin by GC.
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Garlic and onions are medicinal for their allyl sulphides antioxidant and detoxifying activity.
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A compound in the bulb — called diallyl trisulphide — has the power to prevent the destruction of heart tissue.
The Sun
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When consumed, garlic leaves a compound called allyl methyl sulfide in the mouth.
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The Ballyhoura mountain range is the most popular local venue for hill walking and Griston Bog is signposted in Ballylanders.
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Oxidation of allylene to carbon dioxide, as in the case of acetylene, is not easily effected except by the most powerful oxidiz - ing agents, such as calcium hypobromite or potassium permanganate in concentrated sulphuric acid.
Transactions of the American Philosophical Society
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He said, ‘Biddy Early’s cure that you heard of, between the two wheels of Ballylee, it was the moss on the water of the millstream.
Later Articles and Reviews
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To their credit Ballylinan battled hard and after a good break Kieran Kelly scored a fine point to register their second score of the game.
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Decomposition of these primary photoproducts to give secondary products arising from allylic hydroperoxide degradation - either by Hock rearrangement or by alkenyl ether epoxidation - was also observed.
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Now a potent-smelling component of garlic oil called diallyl trisulphide DATS may help "release protective compounds to the heart," stated the researchers, who presented their findings on Wednesday at the American Heart Association's Scientific Sessions in Orlando, Florida.
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He discovered one certain type of solvent called allylic alcohols that turned off the oxidation.
Undefined
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These vegetables contain a number of sulfur-containing compounds, especially allicin and diallyl sulfate, that may fight cancer.
Eat, Drink, and Be Healthy
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There will be a choir practice in Ballylinan on Thursday night at 8pm, for both the folk group and the adult choir.
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This project includes the provision of a new source for the abstraction of water from the River Mahon, at the tidal divide near Ballylaneen.
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These days eyeglass lenses are generally made from lightweight plastics called allyl diglycol carbonate.
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According to the boffins, garlic has no flavour until the cell walls are broken, and when the cell walls are broken, the enzyme alliinase is released, which reacts with a precursor compound, alliin, to form diallyl thiosulfinate and other thiosulfinates the pongy and tasty side of the garlic.
Food for Fort: Talking turkey, and other matters
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There was no denying Ballylinan's superiority as they completely overshadowed an abysmal Rock performance.
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An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol) carried out while she was at Merck.
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He owns the well-known breeding and stallion farm, Ballylinch Stud home of the legendary Tetrarch and part of the Mount Juliet Estate.
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In 1980 he carried out successful experiments that led to a practical method for the catalytic asymmetric oxidation of allylic alcohols to chiral epoxides.
The Nobel Prize in Chemistry 2001 - Information for the Public